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The Coupled Effects of Subsurface Heterogeneities and Nonequilibrium Sorption Processes on Solute Transport

Author(s): Mark A. Cushey; Yoram Rubin

Linked Author(s): Yoram Rubin

Keywords: No Keywords

Abstract: The inter-relationship between heterogeneities in subsurface hydraulic properties and physical nonequilibrium processes associated with the sorption of solutes are analyzed for field-scale transport in three-dimensional porous media. The analysis is completed using a model which couples a stochastic technique for generating three-dimensional flow fields with a mobile-immobile domain model to account for sorption and intraparticle mass diffusion. For statistically isotropic formations, the cumulative distribution function (CDF) of local solute concentrations is found to resemble a truncated normal distribution under certain conditions. For statistically anisotropic formations, the CDF of reactive solute concentrations is found to resemble a log-normal distribution for all cases considered. Tracer concentration CDFs are found to be nonGaussian for all formations and conditions considered.

DOI:

Year: 1997

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